Colloidal Particles: Crystals, Glasses, and Gels

Colloidal particles aremicroscopic solid particles suspended in a fluid. Colloids are small enough that thermal energy drives their dynamics and ensures equilibrationwith the suspending fluid; they are also large enough that their positions andmotions can bemeasured precisely using optical methods, such as light scattering and laser-scanning confocal fluorescence microscopy. Colloidal suspensions are a powerful model system for the study of other phenomena in condensed matter physics, where the collective phase behavior of the solid particles mimics that of other condensed systems. We review three classes of interacting colloidal particles, crystals, glasses, and gels, each ofwhich represents fascinating properties of colloidal particles as well as a model for more general types of materials and their behavior. 217 A nn u. R ev . C on de ns . M at te r Ph ys . 2 01 3. 4: 21 723 3. D ow nl oa de d fr om w w w .a nn ua lr ev ie w s. or g by H ar va rd U ni ve rs ity o n 03 /2 0/ 13 . F or p er so na l u se o nl y.